Images from the La Liga match played between FC Barcelona and Sevilla on at Camp Nou on Sunday
Chile's euphoria at reaching the final of the Copa America was tempered by the reminder that every time they have been in this position before they have finished as runners-up.
Barcelona gave up more ground to Real Madrid in La Liga's title race on Tuesday after being held to a 2-2 draw at home to third-placed Atletico Madrid as a late penalty from Saul Niguez cancelled out Lionel Messi's 700th career goal. The draw meant the Catalans stayed second in the standings on 70 points and leaders Real Madrid, who have 71, will go four points clear at the top with five games left if they beat Getafe at home on Thursday.
Bayern Munich slumped to their first defeat for three months when the Bundesliga leaders suffered a shock 2-1 reverse at home to Mainz 05 on Wednesday.
'They were better than us for some spells and we know what awaits us over there' Valverde pointed to his team's sensational exit from last year's competition to AS Roma after a 4-1 cushion from the first leg and said they would be taking nothing for granted in Tuesday's return game at Anfield.
Barcelona have one hand firmly on the La Liga title after winning 2-0 at Alaves on Tuesday, leaving them 12 points clear at the top of the table with four games to play.
Zenit St Petersburg striker Hulk scored after nine minutes when he muscled his way past a defender and fired home from 12 metres.
Fourth division club Carl Zeiss Jena stunned Hamburg SV 3-2 in the German Cup on Sunday, taking the scalp of the Bundesliga's former European champions to cause the biggest sensation of the competition's first round.
Chile won the Copa America for the first time on Saturday.
Barcelona's last Champions League triumph came in 2015, and since then they have failed to get beyond the quarter-finals while Real Madrid have monopolised the trophy.
After an even first 45 minutes, strikes from Pablo Sarabia and Wissam Ben Yedder stunned the Catalans and left them needing a second-leg comeback at the Nou Camp for the second consecutive round in the competition.
Cristiano Ronaldo and Lionel Messi will resume their perennial battle to be crowned the world's best footballer after they headed the shortlist of 30 players for the 2016 Ballon d'Or announced on Monday.
Andrea Pirlo and Miralem Pjanic provided the moments of magic to inspire leading Serie A duo Juventus and AS Roma to battling victories on Sunday with the gap between the sides remaining at three points.
Chile have never beaten Argentina in open play in 27 Copa America meetings in 100 years yet have twice in 12 months dashed the hopes of Lionel Messi's team of lifting a major trophy.
Not much has thwarted the predatory instincts of Bayern Munich's Thomas Mueller and Robert Lewandowski this season but even that dynamic duo will have their work cut out to pierce the rock-solid Juventus defence on Tuesday.
Lionel Messi scored a record eighth Champions League hat-trick as Barcelona kick-started their campaign with a 4-0 home win over PSV Eindhoven, although they had defender Samuel Umtiti sent off late in the second half on Tuesday.
Juventus need to beat Manchester City to reach the Champions League knockout stages on Wednesday and many fans still believe the best way to achieve this is by fielding Alvaro Morata and Paulo Dybala together in attack.
Leaders Bayern Munich's express start to the season finally ran out of steam on Friday with a goalless draw at Eintracht Frankfurt, following 10 wins out of their 10 previous Bundesliga games.
Hosts Chile brushed aside Bolivia 5-0 at the Copa America on Friday to finish top of Group A and ensure they remain in the capital Santiago for their quarter-final.
Images from Copa America matches played on Monday.
'We aren't playing well and we can't blame the coach, as the players are the ones who have to perform on the pitch'
Chile beat Colombia 2-0 in the Copa America semi-final on Wednesday and will face Argentina in Sunday's final after surviving a tumultuous match in Chicago.
Goals from Gonzalo Higuain and Jose Callejon sent Napoli top of Serie A after they beat Atalanta 2-0 on Saturday while an injury-time Mario Balotelli penalty helped AC Milan come from two goals down to snatch a 2-2 draw at Torino.
Bayern Munich were left to rue a number of missed chances in their Champions League last 16 first leg against Juventus on Tuesday after the Germans squandered a two-goal lead to draw 2-2 despite dominating for much of the game.
Bayern Munich winger Arjen Robben sparkled on his comeback from injury after almost two months, scoring the champions' first goal in a 4-0 demolition of Cologne on Saturday for their 1,000th victory in the Bundesliga that put them 10 points clear at the top.
Brazil playmaker Kaka scored his first goal, a delightful curling shot, since his return to AC Milan at the start of the season but his struggling team were held 1-1 at home by Lazio in Serie A on Wednesday.
Manchester City embark on a fifth Champions League campaign buoyant after a perfect start to their domestic season but still searching for the secret formula against Europe's top brass.
Real Madrid coach Carlo Ancelotti fended off questions about his future after the Champions League holders were dumped out in the semi-finals by Juventus 3-2 on aggregate on Wednesday.
Serge Gnabry scored twice as Bayern Munich beat Chelsea 3-0, while Antoine Griezmann's second-half equaliser handed Barcelona a vital away goal and earned them a 1-1 draw at Napoli in their Champions League last 16, first leg on Tuesday.
Cristiano Ronaldo and Lionel Messi will again be duelling for the title of world's best footballer after their names once again headed the shortlist on Thursday for The Best FIFA Men's Player.
Earlier in the night, Bolivia were denied their first win when Kaku scored with 18 minutes remaining to rescue a 2-2 draw for home side Paraguay in Asuncion.
Photos from the match between Bayern Munich and Juventus played on Wednesday
Barca, who were without injured talisman Lionel Messi, started on the back foot and fell behind when Nabil Fekir netted with a sublime angled strike in the 15th minute. Griezmann, who joined Barca last month from rivals Atletico Madrid, scored four minutes before halftime to level the scores.
Arsenal conceded five goals for the first time at their Emirates Stadium as they suffered their worst home defeat for 19 years.
When Massimiliano Allegri arrived in Turin last July, Juventus ownership had set two goals for him - win a fourth straight "Scudetto" and reach the Champions League quarter-finals.
Juventus made light work of bitter rivals Inter Milan on Sunday, winning 3-1 to increase their Serie A lead to nine points after AS Roma were washed out and Napoli blundered to a 3-0 defeat at Atalanta.
Earlier in the day, Bolivia beat Venezuela 3-1 at home and Uruguay and Paraguay drew 0-0 in Montevideo.
Bayern Munich's party was wrecked by Borussia Moenchengladbach who hit back for a 1-1 draw at the Allianz Arena on Saturday, forcing the Bavarians to wait at least a week to clinch a fourth straight Bundesliga title.
Juventus staged a superb revival to battle back from two goals down and rescue their Champions League hopes with a 2-2 draw against Bayern Munich in their last 16 first leg on Tuesday.
Lionel Messi became the first player to win 10 La Liga crowns with Barcelona and only the third player from any club to do so.